Solvothermal synthesis of new metal organic framework …
2005年11月1日 · Two new metal organic framework (MOF) structures have been obtained from the Zn–terephthalic acid (H 2 BDC)–dimethyl formamide (DMF) system and examined by single-crystal X-ray diffraction: Zn(C 8 H 4 O 4)(C 3 H 7 NO), 1, monoclinic C2/m, a = 11.1369 (5), b = 14.0217 (7), c = 7.9890 (4) Å, β = 106.316 (1) °, V = 1197.3 (1) Å 3, T = 180 ...
A novel Zn-based-MOF for efficient CO 2 adsorption and …
2022年5月1日 · A novel Zn-based-MOF material, called Zn-URJC-8, containing two different organic linkers, 2-aminoterephtallic acid and 4,4-bipyridyl, has been synthetized and used for catalytic purposes for the first time.
Dual hydrogen-bond donor group-containing Zn-MOF for the …
A novel zinc (ii)-based 3D metal organic framework (MOF) [Zn3 (L)3 (H2L)·2DMF·H2O] with dual hydrogen-bond donor (HBD) groups of a free carboxyl and amine, was synthesized solvothermally via 2-aminoterephthalic acid (H2L) and 3,5-pyridinedicarboxylic acid ligands. The carboxyl and amine in the prepared Zn3 (L)3 (.
Two‐Dimensional Metal–Organic Frameworks‐Based …
Recently, 2-aminoterephthalic acid (NH 2-BDC) was selected as the organic ligand to synthesize 2D bimetal MOF (Co x Fe-MOF) NSs, which satisfied the criteria for OER and nitrogen reduction reaction (NRR) concurrently.
Solvothermal synthesis of new metal organic framework …
2005年11月1日 · Solvothermal synthesis has produced two new crystal structures derived from the Zn–terephthalic acid–DMF system. The major synthesis product is the metastable Zn(C 8 H 4 O 4)(C 3 H 7 NO), 1, which converts completely over a period of 12 months to the known crystalline phase MOF-2, the phase obtained by crystallization at ambient conditions ...
Amine-functionalized Zn(ii) MOF as an efficient multifunctional ...
2018年5月21日 · The MOF {[Zn(ATA)(L)·H 2 O]} n (ZnMOF-1-NH 2) has been characterized by various physico-chemical techniques, including SCXRD, and composed of the bipyridyl-based Schiff base (E)-N′-(pyridin-4-ylmethylene)isonicotinohydrazide (L) and 2-aminoterephthalic acid (H 2 ATA) ligands as linkers. The MOF material has been explored as a multifunctional ...
Zinc-based metal-organic frameworks: synthesis and recent …
2022年7月18日 · This review based on Zn-based MOF is summarized on new insights for targeted drug delivery of medicinal compounds and developed for medicinal applications. The stability of the MOF may be controlled by functionalization and the proper structure and composition choices.
Synthesis and characterization of three amino-functionalized …
2015年3月26日 · In this study, three novel amino-functionalized metal–organic frameworks (MOFs): Mg-ABDC [Mg 3 (ABDC) 3 (DMF) 4], Co-ABDC [Co 3 (ABDC) 3 (DMF) 4] and Sr-ABDC [Sr(ABDC)(DMF)] (ABDC = 2-aminoterephthalate) were synthesized by solvothermal reactions of 2-aminoterephthalic acid (H 2 ABDC) with magnesium, cobalt and strontium metal centers ...
(PDF) Zinc-based metal-organic frameworks: synthesis and recent ...
2022年7月18日 · Recent research was shown that Zn-based MOF can be used as a viable delivery system for non-toxic/biocompatible medicines and therapeutic agents in biological and medical applications.
Acid-Modulated Synthesis of High Surface Area Amine …
2020年8月28日 · Acidic modulators are shown to yield significant changes in nuclei formation and crystal growth during MOF particle synthesis by enhancing the solubility of the 2-aminoterephthalic acid ligand in aqueous media through protonation of the amine groups while slightly suppressing the deprotonation of carboxylic acids.